A chemist has developed an "upcycling" method of converting waste plastic bags into nanotubes

Most shoppers probably don't even bother recycling their plastic bags at the local supermarket, but maybe this development will titillate the geek inside everyone. A chemist has created an "upcycling" method of turning the disposable bags into carbon nanotubes, according to New Scientist

Better Plastic Recycling: Come on, recycle me! You almost did it!  Lake County, Illinois
Vilas Ganpat Pol developed his method at the Argonne National Laboratory in Illinois. His secret: cooking small 1-gram pieces of high or low-density polyethylene (HDPE and LDPE) at 1292 degrees F (700 degrees C) for two hours, along with a cobalt acetate catalyst. Such high temperatures break down the chemical bonds of plastic and cause carbon nanotubes to grow on pieces of the catalyst.

The main downside comes from the amount of catalyst required -- about a fifth of the weight of plastic. But the cobalt particles mixed into the nanotubes have the added bonus of making the nanotubes very suitable for use in lithium-air batteries, because the cobalt boosts current flow in batteries.

"The cobalt is not an impurity, it is an asset," Pol told New Scientist. He already holds a patent on the use of cobalt-containing nanotubes in lithium-ion and lithium-air batteries.

Nanotubes have gotten a lot more flexible recently. For instance, Stanford University researchers coated copier paper in ink made of carbon nanotubes and silver nanowires to create bendable, highly conductive storage devices. Nanotubes could also become self-repair tools for electronic circuits in our smart phones and laptops.

Upcycling plastic bags may not become widespread just yet, but hey -- you could still stand to recycle (or at least reuse) those bags.

[via New Scientist]

7 Comments

Okay, quick question how do we get colbalt, or how much waste is created in the process of mining colbat?

Exactly how long were the nanotubes? I can't imagine they would have a long length, but I personally am just waiting for the day I can ride the space elevator into Earth orbit!

I agree with Nikhil we should a drive to recycle enough plastic bags for NASA to build a space elevator

Why is it a downside to have a large amount of catalyst? Catalysts are reusable- they don't get spent in the chemical process. Couldn't you shave the nanotubes off of the cobalt and reuse it?
Also, a NASA scientist told a class of mine that the Van Allen radiation belts would destroy any nanotube-based space elevator. I'm keeping my hopes up, though...

Does this mean that I am not going to be able to buy any more cobolt blue artist paint? I will give up my cobolt blue artist paint if you take these eight hundred billion tons of plastic bags out of my trashcan and replace them with solar panels for my car and roof of my house. If that is a deal, you can pick the bags up tomorrow. I live half way between California and Hawaii.

Let's get some perspective here. The U.S. EPA estimates that there are between 500 billion and 1 trillion plastic bags used annually worldwide. US plastic bag film recycling experts are happy to report that 800 million lbs. of plastic film is recovered for recycling annually in the US (includes all kinds of film, not just bags). These are huge numbers.

Just exactly how many nanotubes made from plastic bags will be needed? I think the number, expressed in weight, will be tiny compared to the problem or to other high volume solutions. A million lbs. seems like it would be a large number in that market. This application is curious and wonderful for what it is. But in the grand scheme of things it hardly seems worthy of a footnote.

I re-use plastic bags I get shopping for all manner of things until they're worn to the point I can't re-use them anymore.

An obvious use is for leftovers. They're even good for foods such as water melons, cantaloupes, or any other roundish fruit you might not eat all at once. I'l smooth a plastic bag into which I've put, say, half a small water melon and twist the neck tightly closed -- lengthens the shelf-life a bit, too. I use them for trash -- and re-use them for the same purpose, emptying them into a trash bin then bringing them back in with me. I use them to store stuff I know I will be leaving stored a long while to protect stuff from dust. I've even seen people make *raincoats* out of large plastic bags, and smaller ones used for rain hats are a common sight where I live (Bangkok) during the rainy season. And I've seen people with nice shoes they didn't want to get wet pull out a couple of [thick] plastic bags, slip them over their feet, then secure them with rubber bands. An attractive bag makes decent gift wrap, too -- and is reusable. Sometimes I've taken an overnight trip somewhere and instead of packing even a small suitcase, I put whatever I want to take with me in a plastic bag and carry that with me, even on airplanes.

I'm sure I'm forgetting plenty of other uses. . . .


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