The annual Tales of the Cocktail convention happened again in New Orleans last week, I seem to recall. And somewhere between the sazeracs and the rusty nails, I attended a series of enlightening seminars (each accompanied by appropriate cocktails, of course).
Harold McGee, author of On Food and Cooking and probably the most famous name in food science, was present at Tales for the first time, to lend his expertise to a deserving cocktail world. He sat on a panel with Audrey Saunders, celebrated owner of New York's Pegu Club, and Tony Conigliaro, who pushes the frontiers of molecular mixology at London's 69 Colebrooke Row. Over the course of 90 minutes, during which Pegu's head bartender Kenta Goto mixed illustrative drinks for the audience, the trio of experts dropped some fascinating and useful tidbits of cocktail science. Here are some highlights.
When shaking up a drink that you want frothy, egg white is your friend, since its proteins bond together permanently to give structure to a foam. Gelatin, the protein more commonly used in culinary foams, tends to melt after a while, since its protein bonds only temporarily. Shake the egg white at room temperature first, since it foams better warmer; then chill the drink. A shaker made of silver produces a softer, more delicate foam because of the metal's interaction with the egg.
To make a champagne cocktail, as we all know, you put a sugar cube at the bottom of a champagne flute, shake a few dashes of Angostura bitters onto the cube, then fill the glass with chilled champagne. Unfortunately, as Goto demonstrated, bitters is full of small molecules, such as lecithin, which cause the champagne's foam to strengthen and grow, so pouring fizz onto bitters can be a messy proposition, releasing too much CO2 from the drink too soon. Instead, Saunders suggests, fill the flute first, then gently gently add a bitters-saturated sugar cube and serve.
McGee cited some useful information for cocktail inventors about how the brain perceives flavor. For one thing, if there's sugar present in a cocktail, the brain will find the drink more aromatic than an identical drink with less sugar. That's an evolutionary adaptation, he theorizes: we are much more interested in items that provide more life-giving calories.
Also, in strong drinks (above 20 percent alcohol), the concentrated ethanol can form large clusters, or micelles, that are dispersed in the water phase. Aroma molecules can hide inside these clusters, becoming trapped, and thus make the drink seem less aromatic and flavorful to the drinker. Diluting the drink helps the alcohol clusters break up, freeing the tasty aroma molecules. (In the Times this week, McGee writes about other instances of diluting for flavor.) Chilling the drink also makes the alcohol more soluble in water, and likewise frees trapped aromatics. That's why putting a couple of ice cubes in a glass of neat whisky does so much for the drink's taste.
Finally, Tony Conigliaro demonstrated a little trick he's been doing for a few years: mixing cocktails, putting them in bottles, and sticking them in a cool cellar for six months or more. (At this point, Kenta Goto obligingly poured out a round of Cuban rum cocktails thus aged.) The drink had a magnificent round, integrated flavor, although it would have been interesting to taste an unaged sample for comparison.
When spirits age in wooden casks, the majority of the changes that take place are due to the liquor's complex interaction with the wood, which gives it color and flavor. But when drinks are aged in glass bottles, they don't interact with the inert container. So what's happening? McGee explained that, left to its own devices, a spirit will age regardless: sulfur compounds in the drink oxidize, and alcohols, acids, and aldehydes react together, losing their harsh edges and producing aromatic esters.
After the McGee seminar, PopSci fave Dave Arnold took the stage for his own seminar, The Science of Stirring, which was nothing more nor less than a detailed analysis of how stirring a drink with ice compares to shaking it (last year he taught The Science of Shaking). Six skilled stirrers (including McGee, who volunteered from the audience) stood on the stage, mixing drinks in vessels Arnold had fitted with thermocouples, while the six drinks' temperatures were plotted live on a giant projection screen.
The liquid nitrogen was brought out at some point as well, to demonstrate that there is indeed such a thing as a cocktail that's too cold. And that was just one morning of the week-long conference. We're lucky we survived.

Five amazing, clean technologies that will set us free, in this month's energy-focused issue. Also: how to build a better bomb detector, the robotic toys that are raising your children, a human catapult, the world's smallest arcade, and much more.


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Stirring vs shaking is not a matter of temperature but the impact it has on the liquor. This is in terms of damaging it (in the case of Gin “bruising” the botanicals) or entraining air (best for vodka). This is why James Bond can get away with having his vodka martini shaken although the reason has to do with the physics involved in women mixing it this way.
Alcohol is a drink for the fool.
"Alcohol is a drink for the fool."
That makes me the court jester. :-)
...and hemlock is the drink of Socrates.
"Alcohol is a drink for the fool."
A wise man speaks because he has something to say; a fool because he has to say something. -Plato
Methinks you are the latter, ScottieD...
"Alcohol is a drink for the fool."
And thaaannnk you Wayne Wheeler for your insight which has been duly noted time and time again...
"Chilling the drink also makes the alcohol more soluble in water"
No, the converse.
@hydr0o:
actually, that is correct. Look up the binary phase diagram for water-ethanol solutions. Higher concentrations of ethanol in water are only available in liquid phase at lower temperatures.