Nano-sized "popcorn balls" could be used to boost the efficiency of solar panels

Solar Cells Each ball that composes the solar cell is about 300 nanometers wide. University of Washington

Hardly a week goes by these days without a new solar panel technology development in the news. You would think the country was plastered in solar sheets with all the work currently being done. Let's hope the stories soon turn to how we're going to make this all affordable enough to support widespread installations. In the meantime, today's innovation.

If you've been following our recent series of articles on solar cells, you've likely noticed the focus falls roughly into two categories: how to make the panels thinner, lighter and more flexible; and how to make the cells more efficient.

Currently, the best we can do on the efficiency scale hovers right around 18 to 20 percent. Scientists are constantly looking for new ways to capture more of that remaining 80-some percent of energy in the sun's rays that goes unclaimed. While the approach the researchers at the University of Washington took was not intended immediately to maximize efficiency, it is at its core a method for capturing more light.

Dye-sensitized solar cells are a type of panel more akin to the thin film sheets we've been seeing recently than to the rigid silicon cells with which we're all familiar. They are very cheap to manufacture, which is their primary selling point. On the other hand, they are about half as efficient as better cells.

In a novel approach to boosting their capabilities, the researchers created "popcorn balls" out of nanometer-sized kernels of light-absorbing material. By clumping hundreds of minuscule grains into clusters of large grains, they were able to harness the advantages of both sizes. The small grains provide a large surface area for maximum absorption, while the large grains are closer to the wavelength of visible light and so ricochet the light into the smaller grains.

The UW scientists discovered the combination effectively doubled the cells' efficiency. Before we celebrate the arrival of a new benchmark of success, we should note that these particular dye-sensitized cells began with an efficiency of 2.4 percent. They used a compound which is very easy to work with, but poor in absorption. The hope is that moving to more difficult but better performing material will eventually lead to breaking that twenty percent barrier.

Via PhysOrg

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2 Comments

University of Delaware created a solar cell with over 40% efficiency and there are many other types of cells with efficiencies anywhere between 10 and 30%. Thin film solar cells and cells using organic dyes are the ones limited to low efficiency.

True, the Delaware team obtained over 40% efficiency, but their cell was a triple-junction device operating under concentrated light. I assume the author was referring to single-junction solar cells when he said 18-20% is currently the best we can do. The best commercial-grade silicon cells currently have efficiencies a little lower than this, so 18-20% is either for lab-grown silicon or commercial III-V single-junction cells.

Also, the author says that these dye-sensitized cells have low efficiencies because of poor absorption. But, isn't the whole purpose of using various size balls to increase the amount of light absorbed by allowing the cell to absorb a wider portion of the light spectrum? I thought I heard somewhere that the reason these new organic, popcorn ball, or quantum dot cells are so inefficient is because of their high rate of recombination. I could be wrong, but I think recombination and absorption are completely different. Someone chime in if they can elaborate.



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